Encryption padding error

[Bob Ross]

I am trying to ecrypt passwords to store them in a DB but I want to store them in String(nvarchar ) format. So I have written this class

    Public Class PasswordEncryption
        Private IV As Byte() = Convert.FromBase64String("pl21q5lX3KvPdKEyss7Za0i2nEdfzfbHvbsxlsKCWbU=")
        Private pKey As Byte() = Convert.FromBase64String("1taYM5kPvxIdvNwBcuQefdiKMlzgqpdgiP/BjG4anVw=")
        Dim Cipher As RijndaelManaged
        Public Sub New()
            Cipher = New RijndaelManaged
            Cipher.KeySize = 256
            Cipher.BlockSize = 256
            Cipher.Mode = CipherMode.CBC
            Cipher.Key = pKey
            Cipher.IV = IV
        End Sub
        Public Function EncryptMessage(ByVal plainText As String) As String
            Dim BR As Byte() = Encoding.Unicode.GetBytes(plainText)
            Dim transform As ICryptoTransform = Cipher.CreateEncryptor()
            Dim cipherText As Byte() = transform.TransformFinalBlock(BR, 0, BR.Length)
            Return Convert.ToBase64String(Cipher.Key)
        End Function
        Public Function DecryptMessage(ByVal cipherText As String) As String
            Dim BR As Byte() = Convert.FromBase64String(cipherText)
            Dim transform As ICryptoTransform = Cipher.CreateDecryptor()
            Dim plainText As Byte() = transform.TransformFinalBlock(BR, 0, BR.Length)
            Return Convert.ToBase64String(plainText)
        End Function
    End Class

But every time I try

            Dim Enc As New PasswordEncryption
            Dim PassEnc As String = Enc.EncryptMessage("hello")
            Dim PassUnEnc As String = Enc.DecryptMessage(PassEnc)

I get "Padding is invalid and cannot be converted" Anyone know how I can fix this?
Tried different padding modes but same error everytime.

[Plater]

I would try to debug until the exact spot where it fails to have the padding, then examine the strings and see where it is getting lost?
What you have seems sound enough, assuming what you're using is a 2-way ciper

[Bob Ross]

I can't examine the strings because I am unable to read encrypted text.

It is getting stuck when it trys to decrypt the string this line

Dim plainText As Byte() = transform.TransformFinalBlock(BR, 0, BR.Length)

[Plater]

EDIT:
Actually, your encrypt function is only returning the key

Return Convert.ToBase64String(Cipher.Key)

Which you can't decrypt.
You should be returning, I *believe* they key AND the encrypted message or at lease the encrypted message.