Short answer is no. Access files cannot be converted to exe files, nor can you convert them to vb/.net as the user forms etc are unique to Access itself - there is no converter I know of that will make a VB project from an Access DB.
Access VBA code can to some extent be used within a VB environment, if you wish to use VB's forms environment to generate your own user forms in place of Access's, but current generation .net VB uses a lot more modular object-based methods than VBA, so even converting from VBA to .net VB code is in some cases far from simple.
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